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Debra Lynn Dadd
Chloramine Reducing Shower FilterQUESTION: I have chloramines in my water. I have been researching vitamin c shower filters. Would a vitamin c shower filter still react with the chlorine in the chloramines to create hydrochloric acid, or would the ammonia have an effect on the reaction? Or would it have a totally different reaction? I have heard that byproducts of vitamin c with chlorine would be dehydroascorbic acid, ammonia and chloride. I have also heard elsewhere that hydrochloric is produced when it comes into contact with vitamin c.
I was looking at a KDF shower filter first with a vitamin c hand-held shower filter after it. What would your opinion be on that kind of setup? Have you found any kind of shower filter that helps to rid the chloramines from the water?
Any information that you could forward would be greatly appreciated.
Thank you POSTED BY CAT :: FLORIDA USA :: 10/07/2006 2:51 AM DEBRA'S ANSWER:
As far as I know, there is NO point-of-use shower filter that removes chloramines. I wish there were, but there isn't.
It's great that you know your water contains chloramines and you are looking for the correct filter. Many people are confused between chlorine and chloramine. For many years chlorine was used to disinfect tap water, and that was easily removed with a good carbon or KDF filter. Now, many communities are switching to chloramines--a combination of chlorine and ammonia--which is NOT removed by standard carbon filters.
Since I have chloramines in my tap water, I did some research to find out how to remove them. Regular carbon and KDF will NOT remove chloramines. A special type of "catalytic carbon" has been developed especially to remove chloramines. This is the only thing I know of that will remove it.
Now about the vitamin C filters. I took a look at them on various websites. Most of them claim to remove chloramines. One website offers some "research" articles, but they cover only chlorine. And since KDF only removes chlorine, the KDF/Vitamin C combo still would only remove chlorine.
A page from the Organic Matter blog has a long discussion on Vitamin C shower filters. In it, the blog owner states that he tested one of the vitamin C shower filters and found 99% chlorine removal but "Unfortunately, there isn't a shower filter in the world that can effectively remove anything but chlorine from your shower. No matter what they may claim. The water that flows through a shower filter is moving far too fast to be filtered with any significance."
I'm inclined to agree with him. I haven't found any evidence of chloramine removal from these filters.
I suspect what is happening is that somewhere along the line some marketing person who didn't know the difference made this claim and it just got passed along.
If you want to remove chloramines from your shower water (and I suggest you do), the only option I know of at this time are whole-house units containing the correct catalytic carbon, such as the unit I have in my own home that I purchased from Go Beyond Organic.
For those of you who who want to remove chlorine from your water, I see no reason not to use a vitamin C filter. They contain phyramceutical grade Vitamin C, which forms a chemical reaction with the chlorine to neutralize it. The effectiveness of Vitamin C as a dechlorination agent has been proven by the EPA. As a filter media, it is natural and biodegradable, low tech, and provides nutrition to skin and hair in addition to removing chlorine. There are several available on the internet. The units at www.vitashowercorp.com seem to contain the most vitamin C, so it will last longer than others. Debra :-)
COMMENTS: hi i am johnny i recently bought a Kdf filter i was wondering if u know what readings it would show with a ppm meter. thanx i would appreciate.
COMMENT FROM DEBRA: I personally don't have this information. Ask the retailer where you bought it, or the manufacturer. POSTED BY JOHNNY ROY :: GEORGIA USA :: 12/18/2007 10:09 AM
There was a study done on ascorbic acid and chloramine (www.lmtf.org/FoLM/Plans/Water/PUCreports/LMJuly6ltrwattachments.pdf)
The results on the test of ascorbic acid on chloramine in water is on page 9 of the report. The resulting ammonia level (NH3) is also shown. Ascorbic acid was effective in neutralizing the chloramine, and at higher doses, in also neutralizing the ammonia. What I can't tell is whether there is enough ascorbic acid delivered by the various "vitamin C" shower filters to achieve similar results.
The neutralization was "nearly instantaneous" according to the report, so running the water through the ascorbic acid may work, but that is an outstanding question as well. POSTED BY LOOKING FOR A SHOWER FILTER :: TEXAS USA :: 01/08/2008 6:52 AM
Here is an answer to the original poster's questions, which were, "would the vitamin c react with the chlorine in the chloramines to create hydrochloric acid?" and (to paraphrase), "what are the byproducts of vitamin c reacting with chlorine?"
To answer the second question first--what are the byproducts of vitamin c reacting withchlorine: when vitamin c reacts with chlorine dissolved in water, the byproducts are dehydroascorbic acid (another form of vitamin c) and hydrochloric acid.
The answer to the first question--would vitamin c react with chloramine to produce hydrochloric acid--is no. when vitamin c reacts with chloramine, the byproducts are dehydroascorbic acid, ammonia, and chloride (a form of chlorine which is essential to the body).
What it boils down to is that if your water has chloramine instead of chlorine in it, you don't have to worry about a vitamin c filter creating hydrochloric acid in your shower.
To go on with the question of whether or not Vitamin C, dissolved in water, will indeed react with both chlorine and chloramine (dissolved in water) to neutralize it--yes, it will.
So a vitamin c shower filter will be effective, but from what I've read on the net, there is some concern as to how long a vitamin C filter would last.
First let's assume that the average shower uses about 15 gallons (57 liters) of water.
In my city, the water has about 2mg/l of total chlorine, so for an average shower, 2mg/l x 57 liters = 114mg of total chlorine which would have to be neutralized.
Now, according to the link that your last poster provided, 3.02mg of vitamin C is needed to reduce 1 mg of total chlorine. so for the 114mg of total chlorine in an average shower in my city, we would need 344mg of vitamin C.
According to the vitacshower website, each one of their shower filters has 210g of vitamin c. that would be enough todechlorinate/dechloraminate a little more than 600 showers. Not too bad.
Of course, that is under ideal conditions, and assuming that the vitamin C is consumed at the exact rate necessary to neutralize the free chlorine. If the vitamin C doesn't dissolve fast enough, then chlorine/chloramine will still remain in the water. if the vitamin C dissolves too quickly, then you are wasting vitamin C and the filter won't last as long as its advertised potential.
Vitamin C is quite soluble, so i would think that more of it gets dissolved than is actually needed to neutralize the free chlorine in your shower water. Plus I'm guessing the designers of the filter would err more on the side of using up too much vitamin c to 1) ensure that all free chlorine is eliminated, and 2) shorter life means more frequent replacements, meaning more revenue for them. so the filter will probably last quite a bit less than 600 showers (at 15 gallons/shower), but without testing one can't know for sure.
Another issue is that vitamin c in solution tends to oxidize with air, so even when you're not taking a shower, some vitamin c may be oxidized into dehyroascorbic acid, again reducing the life of the filter. POSTED BY BBOBBO :: MASSACHUSETTS USA :: 04/01/2008 9:06 AM
Call your water supplier to find out if it is Chloramine or Chlorine. As I understand it Chloramine doesn't smell so some prefer it....but I think I also heard it is not removed with some filters that will take out Chlorine. POSTED BY JULIE :: IN USA :: 04/07/2008 12:53 PM
Aquasmart has a shower filter that filters chloramines.
Go to www.aquasmart.com and scroll down to the botton of page.
Click on the picture of the shower filter.
COMMENT FROM DEBRA: I don't think so. I think they are either being deceptive or just don't understand.
They claim that their shower filter contains KDF 85, which removes chloramine. I went to the website for KDF Fluid Treatment Inc., who is a manufacturer of KDF. They say:
KDF 55 Medium was designed specifically for removing or reducing chlorine and water-soluble heavy metals. It controls scale, bacteria and algae, even in hot water.
KDF 85 Medium removes or reduces iron and hydrogen sulfide from municipal or other water supplies. Also controls scale, bacteria and algae.
KDF 85 clearly doesn't say it removes chloramines.
POSTED BY F. G. :: ONTARIO CANADA :: 04/07/2008 1:46 PM
Hi, I have severe MCS, chloramines in my water and I live in an apartment. The only thing that has worked for me is the vitamin c shower filter. I have tried a number of regular shower filters including the aquasmart filter and have reacted severely to all of them. Now with the vitamin c shower filter if I stay in for a long period of time my skin has a slight itch but it is far more tolerable than the other filters. Since the vitamin c shower filter does not filter toxins I don't stay in it long and also don't have it really hot(I figure my pores won't open and take in as many toxins as well as the filter lasts longer). I'm so grateful for the vitamin c shower filter as I was getting very ill just from having a shower and taking several days to recover from it. POSTED BY HEATHER :: BRITISH COLUMBIA CANADA :: 04/10/2008 1:41 PM
From the site : www.ecologycenter.org/factsheets/waterquality_eastbay.html
Chloramine Removal — Chloramine, unlike chlorine, will not evaporate from water by itself and not all water filters that remove chlorine will remove chloramine. For example, showerhead filters and filter balls that are used in bathtubs do not remove chloramine. Chloramine can be removed for drinking water purposes by a carbon block or activated carbon filter that can be installed on a kitchen faucet. According to the San Francisco Public Utilities District, boiling water for 20 minutes will remove chloramine. A short boil of water to prepare tea or coffee will remove about 30% of chloramine. Adding fruit to a water pitcher, for example slicing peeled oranges into a 1-gal water pitcher will neutralize chloramine within 30 minutes. Both chlorine and chloramine can be removed for bathing purposes by dissolving Vitamin C in the bath water (1000 mg Vitamin C tablet will neutralize chloramine in an average bathtub).
COMMENT FROM DEBRA: Ordinary carbon will NOT NOT NOT remove chloramine. You need a special type of carbon designed to remove chloramine.
POSTED BY KM :: CALIFORNIA USA :: 09/01/2008 3:24 PM
Are there any shower filters that will remove chloramines yet? If not, what else can we do? POSTED BY MATTH :: DISTRICT OF COLUMBIA USA :: 11/24/2008 12:20 PM
A useful article at www.ionizers.org/chlorineremoval.html on the effect of chlorine and the need for chlorine removal states: "Chloramine is already bound to organic matter in the water therefore it cannot bond to skin or hair. There is no chloramine gas therefore no vapors to inhale such as with chlorine." Can anyone confirm this? If it is accurate, the need for shower filtration seems questionable, though the fact that fish and other aquatic organisms are extremely sensitive to chloramine makes me wonder.
POSTED BY SHAMS :: CALIFORNIA USA :: 01/06/2009 8:34 AM
Dear Everyone, Please bear with me-this is long but there's so much to say.
I am with People Concerned About Chloramine [PCAC] (www.vce.org/chloramine ), a grass roots citizens group dedicated to the removal of chloramine from our municipal water. We have over 300 people in my water district who have reported mild to severe skin, respiratory and/or digestive symptoms to us since chloramine replaced chlorine in 4/06.
We are working with citizen groups in other states who are dedicated to the removal of chloramine from their water or from going into their water. San Francisco-based Citizens Concerned About Chloramine [CCAC] (www.chloramine.org ) is the oldest of these groups. They formed shortly after chloramine went into their water in 2/04.
Between just CCAC and PCAC there are around 1000 people who have reported chloramine-related symptoms. Many sufferers have tried various kinds of filtration to remove chloramine, from faucet devices all the way to whole house systems (including me- I had all 3 kinds of symptoms moderately). Some people with mild to moderate symptoms may find some relief, some don't get enough relief to have enough good quality of life, and some get no relief whatsoever. 100% of the sufferers (including myself), however, do experience 100% relief when they expose themselves only to water that never had chloramine in it. The reason is very complicated and depends on several factors and I don't know them all. What I do know, though, is that between CA and VT no one has gotten 100% relief from chloramine symptoms using any kind of filtration. This is a vast chemistry experiment and we are the lab rats.
The one kind of filters Debra recommends are catalytic carbon filters. Here's what I know about them: like any filters, they are not going to remove all the chloramine and the older they get the less they remove. Independent engineers (who are not invested in selling filters) confirm that no filter will remove all the chloramine, including expensive whole house filters utilizing catalytic carbon. From the personal experience of sufferers who install these filters, they do not get complete relief, especially if their symptoms are moderate to severe. Some of these people have done expensive testing on their filtered water and demonstrated that a significant percentage of the chloramine is still coming through these filters, even when the filters are relatively new. The whole house catalytic filters must go on the outside line going into the house or building because they cannot be used with warm or hot water- they don't work with warm or hot water. The larger the building and the more people using the water, the more extensive and expensive the filter must be. Even for a small apartment building the estimated expense of installing such a filtration system was $80,00 to $120,000 and upwards. Imagine a person with limited income affording such a system. For nursling facilities, hospitals, and large apartment buildings, the cost of whole building filtration for such places is so prohibitive that it is virtually not doable. Since no point of use filter is useful for bathing, showering, laundry, etc., low income, fixed income, elderly, disabled people, etc. have no choice and no remedy against chloraminated tap water. For those who are made sick by this chemical in the water, which may be as much as 30% of the population, this represents a major social justice issue. Many of the reactions to chloraminated water are life-threatening.
On the topic of vitamin C shower filters. Because of the warm temperature of the water, the volume of the water passing through the filter, and the speed at which the water passes through the filter, the vitamin C shower head filter cannot possibly catch and convert all of the chloramine into certain forms of chlorine and ammonia. So much of the chloramine gets through that filter. The ammonia that is coming through is problematic for people who are sensitive to chloramine because many times they are also sensitive to the ammonia in the water. The ultimate test of a filter is whether or not people with symptoms experience relief. That's really the acid test.
I personally would not use any kind of filtration with chloraminated water. Here's my filtration story. I tried with a very expensive cold water filter that attached to my kitchen sink faucet that used lots of carbon that the water goes through first, very slowly, and then a reverse osmosis membrane (RO), which is supposed to remove the ammonia part of the chloramine molecule. The company I bought it from (for $355) claimed it removed chloramine, that its carbon filters would last a family of 4 for a year and the RO would last a family of 4 3-5 years. The filter replacement was going to be $200 for the 3 carbon filters and the RO. This is the kind of filter device the general manager of my water district recommended as the only kind of filter that would remove chloramine. He explained that the RO (which wasted about 3x more water than it filtered, making my water bill soar) is the only thing that will remove ammonia from the water. I live alone and it failed after 10 months.
The way I found out it was failing was getting a chronic stomach ache that lasted 2 weeks before it dawned on me that maybe the cause of it was something in the filtered water that the filter was no longer keeping out. Sure enough, using the particle counter that came with it, it showed, for the first time that it was removing 89% of the particles, not 100% like it had read previously. I immediately stopped using it and immediately my stomach ache ceased.
Which leads me to this. Chloramine is a seriously inferior disinfectant to chlorine. The World Health Organization (WHO), says that chloramine is about 2,000 and 100,000 times less effective than chlorine at the inactivation of e.Coli and rota viruses, respectively (W.H.O. Guidelines for Drinking Water Quality Vol.2, 1996, Chapter 16). This is but one quote from very legit sources about chloramine's inability to disinfect well. Chloramine is at the bottom of the EPA's list of acceptable municipal disinfectants because it is such a poor disinfectant. As a result, chloramine is never to be used as a primary disinfectant, but only after a more effective disinfectant, like chlorine or UV light, is applied first, can it be then used in the pipeline distribution system.
I'll probably never know what caused my chronic stomach ache, whether it was a chemical irritation from the chloramine itself or whether I was ingesting pathogens (microorganisms, bacteria, viruses) that were wreaking havoc on my stomach due to there being large colonies of them living in the filter media because chloramine wasn't killing them the way chlorine would have.
Water districts tout that a major benefit of using chloramine is its persistence in the water supply. In other words, it doesn't dissipate as easily as chlorine does, and therefor it does not need to be refreshed as often. This saves water districts money. But the downside for the consumer is that since chloramine persists so doggedly in the water, it is nearly impossible to remove and very expensive.
Since chloramine is such an ineffective disinfectant, much higher doses of chloramine are typically used in water systems than were needed with chlorine.
The best remedy for chloraminated water is NOT filtration. The best remedy is to prevent water districts and the EPA from allowing the use of an untested chemical like chloramine at all. To that end our groups are working diligently. Please support us.
COMMENT FROM DEBRA: Thank you for writing. Water quality is an ongoing issue. Tap water has many problems that are NOT solved 100% by filtration, but I find that it is a better option than bottled water. I TOTALLY agree with you that the solution is not filtration, but rather, less polluted water coming from our taps. Chlorine as a disinfectant is a lot easier to remove than chloramine. I support you in your work.
POSTED BY ELLEN POWELL :: VERMONTERS FOR A CLEAN ENVIRONMENT :: VCE.ORG/CHLORAMINE :: VERMONT USA :: 01/13/2009 2:46 AM
Can you please take a look at this link for chloramine reducing filters, and let me know what you think? www.filtersfast.com/Chlor-Plus-Series.pdf
Also, does Winston Kao's Go Beyond Organicwhole-house filter remove chloramines? How does this system work?
Thank you
COMMENT FROM DEBRA: First, yes, Winston's whole-house filter and undersink filters remove chloramines.
The important thing here to know is that there are two kinds of carbon: one for chlorine and one for chloramines. If you have chloramines in your water, you need a cartridge with the chloramine-type carbon, such as in the link that you provided. There are other brands as well.
The question of the original post, however, was regarding a chloramine SHOWER filter, which has been difficult to find. I just remembered something, though, reading your comment.
Before shower filters were ever made commercially, my father actually invented a shower filter for me, and that's how they came to be. We used an undersink filter housing and changed the fittings to mount it on the shower. It was ugly, but did the job. I didn't care how it looked--I could finally take a shower. You could get the undersink filter in which these housings fit and change the fittings to mount on the shower. That would do it.
POSTED BY CAT :: FLORIDA USA :: 01/20/2009 9:50 AM
Well as a friend of mine said....her Amish friend told her if their heat/electricity ever gave out, she could come and stay with them. This kind of thinking could be applied to this problem as well. At the very least, it would seem that one could get water from a sink filter that they already had, heat it and use it in the tub as sort of a deluxe sponge bath. If this sounds way too primitive, you haven't had severe chemical issues or been camping or been hospitalized and unable to take a real bath or shower. It feels pretty good when that is all you have.
COMMENT FROM DEBRA: I want to second the idea that a sponge bath may be entirely adequate.
Showers are a very recent invention in the history of bathing. The first shower wasn't installed until 1810 in England. Yet today, millions of gallons of water cycle through our homes just for a shower.
Prior to showers, people bathed in bathtubs filled with water that had been heated on the stove. And before that, people bathed in streams and under waterfalls.
I think it's time to rethink the necessity of showers.
POSTED BY JULIE :: INDIANA USA :: 01/21/2009 9:28 AM
I have been developed a device for feeding ascorbic acid (vitamin C) to the feed water of an RO system used for kidney dialysis application in order to eliminate the chlorine and chloramine. The limit for dialysis is 0.1 ppm chloramine. For this application we include an ORP (oxidation reduction potential) electrode and monitor to verify the effectiveness on line.
In researching the overall topic of chloramine I came across concerns and ads for technology to remove the chloramine for domestic uses, especially showers. We have used catalytic activated carbon for more than 10 years in dialysis water systems. It is effective, but it is bulky, heavy, expensive and has high operating costs.
In comparison our ROducer vitamin C feeder is affordable and very inexpensive to operate. For example a 10 minute shower using a 3 GPM shower head and water containing 2 ppm of chloramine would use less than 5 cents of Vitamin C powder!
Other than a volume to allow a 30 second reaction time, the feeder weighs only a few pounds and has no moving parts. The vitamin C is held in a refillable clear plastic tube.
We are now developing a prototype shower unit. It will be approximately 26 inches wide by 28 inches high, 5 inches deep and the whole thing should weigh about 25#. It could be mounted on the wall below the shower head or even hung from the shower head against the wall. At a 3 GPM nominal flowrate, the pressure drop will be less than 5 PSI. Connection to the shower head will be very easy. It will handle water much hotter than a typical shower. We expect the price to be about $750.
The standard test for chloramine is the DPD reagent test. First the total chlorine level is measured and then the free chlorine level is subtracted. Since the free chlorine is so much more easily and quickly removed, there is really no point in performing more than the total chlorine test. A package of reagent pillows for 100 tests is about $25 and is available from hach.com.
Feel free to contact me if you are interested in this.
POSTED BY STEPHEN C. CARR :: :: AWEWATER.COM :: UTAH USA :: 02/10/2009 4:59 AM
In this blog you state that kdf 85 does not remove chloramine from water. However I found this on the kdf website.
www.kdfft.com/pdfs/Reductive_Dechloramination.pdf
If you have time I would appreciate you checking it out and letting me know your thoughts. As another poster pointed out, aquasmart makes a kdf 85 filter so if the above info is correct, perhaps we have found a shower filter that will take out chloramine?
Also you had mentioned a concern over possible copper leaching from the kdf into the water. Were you ever able to find out one way or the other as that is a big concern too. What good is filtering out chloramine if you are adding something else just as bad!
thanks
COMMENT FROM DEBRA:
I did take a look at the link you provided.
First, I want to note that they say that chloramine more difficult to use than chlorine as a disinfectant because chloramine requires contact time 100 times longer than chlorine to deactivate coliforms. "For this reason the USEPA recommended that chloramine not be used as a primary disinfectant." It also is more persistent than chlorine, and so has a longer life within a water supply.
This study does not show that ordinary KDF in any currently existing filter removes chloramine. It gives the result of tests that were done to determine IF their KDF could remove chloramine as well as chorine. The conclusion states the conditions that would be necessary to acheive chloramine removal with KDF. They are looking at questions like how much KDF would you need to have a long enough contact time to remove chloramines. They also note that a unit would have to backwash once a day to refresh the KDF, using additional water. It IS possible to use KDF to remove chloramines, but I'm not sure they established it would be practical.
I noted their homepage says, KDF can be used to safely "reduce or remove chlorine, iron, hydrogen sulfide, heavy metals, and bacteria." Chloramine is not on their list of pollutants which they represent can be removed.
I don't have an answer for you about the copper leaching.
POSTED BY JEN :: COLORADO USA :: 10/29/2009 3:13 PM :: POST YOUR COMMENT
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